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The electron configuration for copper is 1s 2 2s 2 2p 6 3s 2 3p 6 4s 1 3d 10 or given in terms of a noble gas configuration which is [Ar]4s 1 3d 10 and not [Ar]4s 2 3d 9, as would be expected from the Aufbau principle. The loss of the electron from the 4s orbital completes the 3d sub-orbital and leaves it in a more stable, lower energy state.
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